| France | 2 | 0 | Spain |
| R1 – G.MONFILS (FRA) def. D.FERRER (ESP) 7-6(3) 6-2 4-6 5-7 6-4 |
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| R2 – M.LLODRA (FRA) def. F.VERDASCO (ESP) 6-7(5) 6-4 6-3 7-6(2) |
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| R3 – J.BENNETEAU / M.LLODRA (FRA) v. F.LOPEZ / F.VERDASCO (ESP) | |||
| R4 – G.MONFILS (FRA) v. F.VERDASCO (ESP) | |||
| R5 – M.LLODRA (FRA) v. D.FERRER (ESP) | |||
| Russia | 1 | 1 | Argentina |
| R1 – D.NALBANDIAN (ARG) def. N.DAVYDENKO (RUS) 6-4 7-6(5) 7-6(6) |
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| R2 – M.YOUZHNY (RUS) def. L.MAYER (ARG) 6-3 6-1 6-4 |
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| R3 – T.GABASHVILI / I.KUNITSYN (RUS) v. D.NALBANDIAN / H.ZEBALLOS (ARG) | |||
| R4 – N.DAVYDENKO (RUS) v. L.MAYER (ARG) | |||
| R5 – M.YOUZHNY (RUS) v. D.NALBANDIAN (ARG) | |||
| Croatia | 1 | 1 | Serbia |
| R1 – N.DJOKOVIC (SRB) def. I.LJUBICIC (CRO) 7-6(3) 6-4 6-1 |
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| R2 – M.CILIC (CRO) def. V.TROICKI (SRB) 6-4 7-5 6-2 |
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| R3 – I.DODIG / A.VEIC (CRO) v. J.TIPSAREVIC / N.ZIMONJIC (SRB) | |||
| R4 – M.CILIC (CRO) v. N.DJOKOVIC (SRB) | |||
| R5 – I.LJUBICIC (CRO) v. V.TROICKI (SRB) | |||
| Chile | 0 | 2 | Czech Republic |
| R1 – I.MINAR (CZE) def. N.MASSU (CHI) 6-0 6-2 6-3 |
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| R2 – J.HAJEK (CZE) def. P.CAPDEVILLE (CHI) 6-0 6-2 6-1 |
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| R3 – J.AGUILAR / P.CAPDEVILLE (CHI) v. F.CERMAK / L.DLOUHY (CZE) | |||
| R4 – N.MASSU (CHI) v. J.HAJEK (CZE) | |||
| R5 – P.CAPDEVILLE (CHI) v. I.MINAR (CZE) | |||