| France defeated Spain 5-0 in France | |||
| R1 – G.MONFILS (FRA) def. D.FERRER (ESP) 7-6(3) 6-2 4-6 5-7 6-4 |
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| R2 – M.LLODRA (FRA) def. F.VERDASCO (ESP) 6-7(5) 6-4 6-3 7-6(2) |
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| R3 – J.BENNETEAU / M.LLODRA (FRA) def. F.LOPEZ / F.VERDASCO (ESP) 6-1 6-2 6-7(6) 7-6(5) |
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| R4 – G.SIMON (FRA) def. N.ALMAGRO (ESP) 7-6(4) 7-6(7) |
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| R5 – J.BENNETEAU (FRA) def. F.LOPEZ (ESP) 7-6(3) 6-4 |
| Argentina defeated Russia 3-2 in Russia | |||
| R1 – D.NALBANDIAN (ARG) def. N.DAVYDENKO (RUS) 6-4 7-6(5) 7-6(6) |
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| R2 – M.YOUZHNY (RUS) def. L.MAYER (ARG) 6-3 6-1 6-4 |
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| R3 – E.SCHWANK / H.ZEBALLOS (ARG) def. N.DAVYDENKO / I.KUNITSYN (RUS) 7-6(7) 6-4 6-7(3) 6-1 |
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| R4 – N.DAVYDENKO (RUS) def. E.SCHWANK (ARG) 4-6 6-3 6-1 6-4 |
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| R5 – D.NALBANDIAN (ARG) def. M.YOUZHNY (RUS) 7-6(5) 6-4 6-3 |
| Serbia defeated Croatia 4-1 in Croatia | |||
| R1 – N.DJOKOVIC (SRB) def. I.LJUBICIC (CRO) 7-6(3) 6-4 6-1 |
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| R2 – M.CILIC (CRO) def. V.TROICKI (SRB) 6-4 7-5 6-2 |
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| R3 – J.TIPSAREVIC / N.ZIMONJIC (SRB) def. M.CILIC / I.DODIG (CRO) 6-3 6-2 6-4 |
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| R4 – N.DJOKOVIC (SRB) def. M.CILIC (CRO) 6-3 6-3 6-2 |
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| R5 – J.TIPSAREVIC (SRB) def. A.VEIC (CRO) |
| Czech Republic defeated Chile 4-1 in Chile | |||
| R1 – I.MINAR (CZE) def. N.MASSU (CHI) 6-0 6-2 6-3 |
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| R2 – J.HAJEK (CZE) def. P.CAPDEVILLE (CHI) 6-0 6-2 6-1 |
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| R3 – L.DLOUHY / J.HAJEK (CZE) def. J.AGUILAR / N.MASSU (CHI) 7-6(3) 6-3 3-6 6-3 |
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| R4 – J.AGUILAR (CHI) def. L.DLOUHY (CZE) 6-1 7-6(6) |
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| R5 – I.MINAR (CZE) def. C.SAAVEDRA-CORVALAN (CHI) 7-6(2) 6-2 |