| Frankrig | 3 | 0 | Spanien |
| R1 – G.MONFILS (FRA) def. D.FERRER (ESP) 7-6(3) 6-2 4-6 5-7 6-4 |
|||
| R2 – M.LLODRA (FRA) def. F.VERDASCO (ESP) 6-7(5) 6-4 6-3 7-6(2) |
|||
| R3 – J.BENNETEAU / M.LLODRA (FRA) def. F.LOPEZ / F.VERDASCO (ESP) 6-1 6-2 6-7(6) 7-6(5) |
|||
| R4 – G.MONFILS (FRA) v. F.VERDASCO (ESP) | |||
| R5 – M.LLODRA (FRA) v. D.FERRER (ESP) | |||
| Rusland | 1 | 2 | Argentina |
| R1 – D.NALBANDIAN (ARG) def. N.DAVYDENKO (RUS) 6-4 7-6(5) 7-6(6) |
|||
| R2 – M.YOUZHNY (RUS) def. L.MAYER (ARG) 6-3 6-1 6-4 |
|||
| R3 – E.SCHWANK / H.ZEBALLOS (ARG) def. N.DAVYDENKO / I.KUNITSYN (RUS) 7-6(7) 6-4 6-7(3) 6-1 |
|||
| R4 – N.DAVYDENKO (RUS) v. L.MAYER (ARG) | |||
| R5 – M.YOUZHNY (RUS) v. D.NALBANDIAN (ARG) | |||
| Kroatien | 1 | 2 | Serbien |
| R1 – N.DJOKOVIC (SRB) def. I.LJUBICIC (CRO) 7-6(3) 6-4 6-1 |
|||
| R2 – M.CILIC (CRO) def. V.TROICKI (SRB) 6-4 7-5 6-2 |
|||
| R3 – J.TIPSAREVIC / N.ZIMONJIC (SRB) def. M.CILIC / I.DODIG (CRO) 6-3 6-2 6-4 |
|||
| R4 – M.CILIC (CRO) v. N.DJOKOVIC (SRB) | |||
| R5 – I.LJUBICIC (CRO) v. V.TROICKI (SRB) | |||
| Chile | 0 | 3 | Tjekkiet |
| R1 – I.MINAR (CZE) def. N.MASSU (CHI) 6-0 6-2 6-3 |
|||
| R2 – J.HAJEK (CZE) def. P.CAPDEVILLE (CHI) 6-0 6-2 6-1 |
|||
| R3 – L.DLOUHY / J.HAJEK (CZE) def. J.AGUILAR / N.MASSU (CHI) 7-6(3) 6-3 3-6 6-3 |
|||
| R4 – N.MASSU (CHI) v. J.HAJEK (CZE) | |||
| R5 – P.CAPDEVILLE (CHI) v. I.MINAR (CZE) | |||